2018年10月19日星期五

Energy content of biofuel

The Energy content of biofuel is a description of the potential energy contained in a given biofuel, measured per unit mass of that fuel, as specific energy, or per unit of volume of the fuel, as energy density. A biofuel is a fuel, produced from living organisms. Biofuels include bioethanol, an alcohol made by fermentation—often used as a gasoline additive, and biodiesel, which is usually used as a diesel additive. Specific energy is energy per unit mass, which is used to describe the energy content of a fuel, expressed in SI units as joule per kilogram (J/kg) or equivalent units. Energy density is the amount of energy stored in a fuel per unit volume, expressed in SI units as joule per litre (J/L) or equivalent units.

Energy and CO2 output of common biofuels
The table below includes entries for popular substances already used for their energy, or being discussed for such use.

The second column shows specific energy, the energy content in megajoules per unit of mass in kilograms, useful in understanding the energy that can be extracted from the fuel.

The third column in the table lists energy density, the energy content per liter of volume, which is useful for understanding the space needed for storing the fuel.

The final two columns deal with the carbon footprint of the fuel. The fourth column contains the proportion of CO2 released when the fuel is converted for energy, with respect to its starting mass, and the fifth column lists the energy produced per kilogram of CO2 produced. As a guideline, a higher number in this column is better for the environment. But these numbers do not account for other green house gases released during burning, production, storage, or shipping. For example, methane may have hidden environmental costs that are not reflected in the table.

Fuel TypeSpecific energy
(MJ/kg)
Energy Density
(MJ/L)
CO2 Gas made from Fuel Used
(kg/kg)
Energy per CO2
(MJ/kg)
Solid Fuels
Bagasse (Cane Stalks)9.6 ~+40%(C6H10O5)n+15%(C26H42O21)n+15%(C9H10O2)n1.307.41
Chaff (Seed Casings)14.6   
Animal Dung/Manure10- 15   
Dried plants (C6H10O5)n10 – 161.6 - 16.64IF50%(C6H10O5)n+25%(C26H42O21)n+25%(C10H12O3)n1.845.44-8.70
Wood fuel (C6H10O5)n16 – 212.56 - 21.84IF45%(C6H10O5)n+25%(C26H42O21)n+30%(C10H12O3)n1.888.51-11.17
Charcoal30 85-98% Carbon+VOC+Ash 3.638.27
Liquid Fuels
Pyrolysis oil17.521.35(Assumption Of Fuel: Carbon Content = 23% w/w) 0.8420.77
Methanol (CH3-OH)19.9 – 22.715.91.3714.49-16.53
Ethanol (CH3-CH2-OH)23.4 – 26.818.4 - 21.21.9132.25-34.03
EcaleneTM28.422.775%C2H6O+9%C3H8O+7%C4H10O+5%C5H12O+4%Hx 2.0314.02
Butanol(CH3-(CH2)3-OH)3629.22.3715.16
Fat37.65631.68  
Biodiesel37.833.3 – 35.7~2.85~13.26
Sunflower oil (C18H32O2)39.4933.18(12%(C16H32O2)+16%(C18H34O2)+71%(LA)+1%(ALA))2.8114.04
Castor oil (C18H34O3)39.533.21(1%PA+1%SA+89.5%ROA+3%OA+4.2%LA+0.3%ALA)2.6714.80
Olive oil (C18H34O2)39.25 - 39.8233 - 33.48(15%(C16H32O2)+75%(C18H34O2)+9%(LA)+1%(ALA))2.8014.03
Gaseous Fuels
Methane (CH4)55 – 55.7(Liquefied) 23.0 – 23.3(Methane leak exerts 23 × greenhouse effect of CO2) 2.7420.05-20.30
Hydrogen (H2)120 – 142(Liquefied) 8.5 – 10.1(Hydrogen leak slightly catalyzes ozone depletion) 0.0 
Fossil Fuels (comparison)
Coal29.3 – 33.539.85 - 74.43(Not Counting:CO, NOx, Sulfates & Particulates) ~3.59~8.16-9.33
Crude Oil41.86828 – 31.4(Not Counting:CO,NOx,Sulfates & Particulates) ~3.4~12.31
Gasoline45 – 48.332 – 34.8(Not Counting:CO,NOx,Sulfates & Particulates) ~3.30~13.64-14.64
Diesel48.140.3(Not Counting:CO,NOx,Sulfates & Particulates) ~3.4~14.15
Natural Gas38 – 50(Liquefied) 25.5 – 28.7(Ethane, Propane & Butane N/C:CO,NOx & Sulfates) ~3.00~12.67-16.67
Ethane (CH3-CH3)51.9(Liquefied) ~24.02.9317.71
Nuclear fuels (comparison)
Uranium-235 (235U)77,000,000(Pure)1,470,700,000[Greater for lower ore conc.(Mining, Refining, Moving)] 0.0~55- ~90
Nuclear fusion (2H-3H)300,000,000(Liquefied)53,414,377.6(Sea-Bed Hydrogen-Isotope Mining-Method Dependent) 0.0 
Fuel Cell Energy Storage (comparison)
Direct-Methanol4.54663.6~1.37~3.31
Proton-Exchange (R&D)up to 5.68up to 4.5(IFF Fuel is recycled) 0.0 
Sodium Hydride (R&D)up to 11.13up to 10.24(Bladder for Sodium Oxide Recycling) 0.0 
Battery Energy Storage (comparison)
Lead-acid battery0.108~0.1(200-600 Deep-Cycle Tolerance) 0.0 
Nickel-iron battery0.0487 - 0.11270.0658 - 0.1772(<40y Life)(2k-3k Cycle Tolerance IF no Memory effect) 0.0 
Nickel-cadmium battery0.162 - 0.288~0.24(1k-1.5k Cycle Tolerance IF no Memory effect) 0.0 
Nickel metal hydride0.22 - 0.3240.36(300-500 Cycle Tolerance IF no Memory effect) 0.0 
Super iron battery0.33(1.5 * NiMH) 0.54(~300 Deep-Cycle Tolerance) 0.0 
Zinc-air battery0.396 - 0.720.5924 - 0.8442(Recyclable by Smelting & Remixing, not Recharging) 0.0 
Lithium ion battery0.54 - 0.720.9 - 1.9(3-5 y Life) (500-1k Deep-Cycle Tolerance) 0.0 
Lithium-Ion-Polymer0.65 - 0.87(1.2 * Li-Ion)1.08 - 2.28(3-5 y Life) (300-500 Deep-Cycle Tolerance) 0.0 
Lithium iron phosphate battery    
DURACELL Zinc-Air1.0584 - 1.59125.148 - 6.3216(1-3 y Shelf-life) (Recyclable not Rechargeable) 0.0 
Aluminium battery1.8 - 4.7887.56(10-30 y Life) (3k+ Deep-Cycle Tolerance) 0.0 
PolyPlusBC Li-Aircell3.6 - 32.43.6 - 17.64(May be Rechargeable)(Might leak sulfates) 0.0 

Notes
While all CO2 gas output ratios are calculated to within a less than 1% margin of error(assuming total oxidation of the carbon content of fuel), ratios preceded by a Tilde (~) indicate a margin of error of up to (but no greater than) 9%. Ratios listed do not include emissions from fuel plant cultivation/Mining, purification/refining and transportation. Fuel availability is typically 74–-84.3% NET from source Energy Balance.
While Uranium-235 (235U) fission produces no CO2 gas directly, the indirect fossil fuel burning processes of Mining, Milling, Refining, Moving & Radioactive waste disposal, etc. of intermediate to low-grade uranium ore concentrations produces some amount of carbon dioxide. Studies vary as to how much carbon dioxide is emitted. The United Nations Intergovernmental Panel on Climate Change reports that nuclear produces approximately 40 g of CO2 per kilowatt hour (11 g/MJ, equivalent to 90 MJ/kg CO2e). A meta-analysis of a number of studies of nuclear CO2 lifecycle emissions by academic Benjamin K. Sovacool finds nuclear on average produces 66 g of CO2 per kilowatt hour (18.3 g/MJ, equivalent to 55 MJ/kg CO2e). One Australian professor claims that nuclear power produces the equivalent CO2 gas emissions per MJ of net-output-energy of a Natural Gas fired power station. Prof. Mark Diesendorf, Inst. of Environmental Studies, UNSW.

Yields of common crops associated with biofuels production

CropOil
(kg/ha)
Oil
(L/ha)
Oil
(lb/acre)
Oil
(US gal/acre)
Oil per seeds
(kg/100 kg)
Melting Range (°C)Iodine
number
Cetane
number
Oil /
Fat
Methyl
Ester
Ethyl
Ester
Groundnut    (Kernel)42     
Copra    62     
Tallow     35 - 42161240 - 6075
Lard     32 - 36141060 - 7065
Corn (maize)14517212918 -5-10-12115 - 12453
Cashew nut14817613219      
Oats18321716323      
Lupine19523217525      
Kenaf23027320529      
Calendula25630522933      
Cotton27332524435(Seed)13-1 - 0-5-8100 - 11555
Hemp30536327239      
Soybean3754463354814-16 - -12-10-12125 - 14053
Coffee38645934549      
Linseed (flax)40247835951 -24  178 
Hazelnuts40548236251      
Euphorbia44052439356      
Pumpkin seed44953440157      
Coriander45053640257      
Mustard seed4815724306135     
Camelina49058343862      
Sesame5856965227450     
Safflower65577958583      
Rice69682862288      
Tung oil tree790940705100 -2.5  168 
Sunflowers80095271410232-18 - -17-12-14125 - 13552
Cocoa (cacao)8631,026771110      
Peanuts8901,059795113 3  93 
Opium poppy9781,163873124      
Rapeseed1,0001,19089312737-10 - 5-10 - 0-12 - -297 - 11555 - 58
Olives1,0191,212910129 -12 - -6-6-877 - 9460
Castor beans1,1881,4131,061151(Seed)50-18  85 
Pecan nuts1,5051,7911,344191      
Jojoba1,5281,8181,365194      
Jatropha1,5901,8921,420202      
Macadamia nuts1,8872,2461,685240      
Brazil nuts2,0102,3921,795255      
Avocado2,2172,6381,980282      
Coconut2,2602,6892,018287 20 - 25-9-68 - 1070
Chinese Tallow[nc 2] 4,700 500      
Oil palm5,0005,9504,46563520-(Kernal)3620 - 40-8 - 21-8 - 1812 - 9565 - 85
Algae 95,000 10,000[citation needed]      
CropOil
(kg/ha)
Oil
(L/ha)
Oil
(lb/acre)
Oil
(US gal/acre)
Oil per seeds
(kg/100 kg)
Melting Range (°C)Iodine
number
Cetane
number
Oil /
Fat
Methyl
Ester
Ethyl
Ester

Notes
Typical oil extraction from 100 kg of oil seeds
Chinese Tallow (Sapium sebiferum, or Tradica Sebifera) is also known as the "Popcorn Tree"

Source from Wikipedia

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